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1.A new type of polymetalatosilicate which contains three different metals-tungsten,molybdenum and vanadium-has been prepared. The compound β-Na9 [HSiW9O34 ]·23H2O which has vacant addend sites was first prepared by the reaction of Na2WO4·2H2O and Na2SiO3·9H2O. Then appropriate amounts of molybdate and vanadate were added to form products of precise Keggin structure.
本文合成了一类未见报道的含三种齿顶原子的钼钒硅酸四丁基铵(TBA)盐,它们是:(TBA)_4[HSiW_9Mo_2VO_(40)]和(TBA)_4[H_2SiW_9MoV_2O_(40)]。收藏指正
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