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2.After stereoselective reduction of cephalotaxinone (─)with sodium boron hydride the goal compound,cephalotaxine(─)had the same configuration as natural cephalotaxine obtains and was verified by 1HNMR,13CNMR,MS,IR specta data,opticity and elementary analysis.
将拆分的三尖杉酮碱(─)旋光体用NaBH4立体选择性还原为三尖杉碱(─),其光谱数据,理化参数,旋光性均与天然三尖杉碱一致。收藏指正
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