broad peak
2.Excitation and Emission spectrum were obtained by using F-4500 fluorometer. Compared with aluminum of not oxidize , the former has a broad peak band at about 280 nm~340 nm and a second peak at 253.8 nm in excitation spectrum, including a broad peak band at 417.4 nm in emission spectrum, while the latter without any obvious peak in either excitation or emission spectrum.
4.At low temperature(2-12 K) some physical parameters, such as Debye temperature QD, Fermitemperature TF and Fermi energy EF, were calculated by means of datacurve fitting. In the Cp-T curves at medium temperature (50-90 K) the specific heat anomaly was observed in the temperature region of 60-85 K, during which the %(T) curve has been known to show a broad peak concerned with thespin-gap of CuC>2 chain.

