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1.The negative thermal expansion (NTE) in some complex oxides has been attributed to transverse thermal motion of A-O-M linkage composed of two-coordinate Oxygen bridge bond, and the librations and tilts of essentially rigid polyhedral blocks in open framework structure.
氧化物的负热膨胀性(NTE)是由于在其开放式的骨架结构中,有二配位的桥氧键产生横向热运动,以及引起的多面体热摆动和耦合作用使非键合M-M1键距变短,导致单胞体积缩小;收藏指正
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