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1.Abstract: By compressing a monolayer film,the coexistence of liquid condensed (LC) and liquid expanded (LE) phases can be reached.The transition from LE to LC is usually regarded as a first-order one,so the theory of crystallization can be applied.In this article we review our recent studies on the growth of LC domains in the LE-LC coexistence region driven by the illumination of a fluorescent microscope.The mechanism of this unusual 2D domain growth phenomenon is discussed.The formation of faceted, dendritic and fractal-like domains as well as the evolution and the transition of these patterns are investigated.
文摘:当处于气液界面的类脂类化合物的单分子膜被压缩时,随着分子间距的缩小,单分子膜将经历一系列相变过程.通过荧光显微术可以观测到新相的成核和生长过程.由于单分子膜的二维特性,该系统中的实验观测对于检验和发展二维界面生长理论尤为重要.本文总结了近年来本课题组与相关单位合作,在单分子膜系统中发现的实验现象以及对其生长机制的系列研究.内容包括对单分子膜系统中的成核、界面稳定性、枝晶生长、形态演变等的观测和分析.收藏指正
2.By compressing a monolayer film,the coexistence of liquid condensed (LC) and liquid expanded (LE) phases can be reached.The transition from LE to LC is usually regarded as a first-order one,so the theory of crystallization can be applied.In this article we review our recent studies on the growth of LC domains in the LE-LC coexistence region driven by the illumination of a fluorescent microscope.The mechanism of this unusual 2D domain growth phenomenon is discussed.The formation of faceted, dendritic and fractal-like domains as well as the evolution and the transition of these patterns are investigated.
当处于气液界面的类脂类化合物的单分子膜被压缩时,随着分子间距的缩小,单分子膜将经历一系列相变过程.通过荧光显微术可以观测到新相的成核和生长过程.由于单分子膜的二维特性,该系统中的实验观测对于检验和发展二维界面生长理论尤为重要.本文总结了近年来本课题组与相关单位合作,在单分子膜系统中发现的实验现象以及对其生长机制的系列研究.内容包括对单分子膜系统中的成核、界面稳定性、枝晶生长、形态演变等的观测和分析.收藏指正
3.The fluorescence spectra of the complexes were measured. The fluorescent emission peaks of the complexes are at nearly 481 and 576 nm corresponding to the 4F 9/2 → 6H 15/2 and 4F 9/2 → 6H 13/2 transition of Dy 3+ respectively,indicating that the complexes emit the characteristic fluorescence of Dy(Ⅲ).
测定了配合物的荧光光谱 ,配合物的荧光发射峰位于 481和 5 76nm附近 ,分别相应于Dy3+ 的 4 F9/2 → 6H15/2 和 4 F9/2 → 6H13/2 跃迁 ,说明配合物发射Dy(Ⅲ)的特征荧光收藏指正
4.First,we have studied the transition of inter molecule energy between the medical and the lanthanide ions Tb and Eu3+ and the complexes can emit the characteristic fluorescence of Tb3+ and Eu3+, so the complexes of them can be used to determin HSA as a kind of fluorescent probe.
第一章,运用荧光分光光度法研究药物与(Eu~(3+)、Tb~(3+))存在分子能量转移,而人血清蛋白(HSA)可以显著增加体系的荧光强度,表明HSA与药物及镧系离子之间发生了相互作用,将其作为荧光探针测定HSA。收藏指正
5.The transition-metal complexes is one kind of important nucleic acid probe and has been developed to be one of the important research field in resent years, it has been used to study aberrance of chromosome,examine tumour and virus, and used as fluorescent probe to detect the structure of DNA.
过渡金属离子配合物作为核酸探针是近年来发展起来的一个重要研究领域,某些手性金属配合物能作为荧光探针,对不同类型的DNA进行选择性分子识别,在探索DNA的结构、作用机理及其功能,染色体变异检测、肿瘤分子检测、病毒检测等方面都有广泛应用。收藏指正
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