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1.1, 8-Octadiol obtained by reducing octandioic acid with LiAlH_4, was selectively oxidized with Ag_2CO_3 celite to give 8-hydroxy octyl aldehyde which was acetyiated with acetic anhydride and then was condensed with propanedioic acid to give 10-hydroxy-2-decanoic acid after hydrolysis.
以辛二酸为原料,经过LiAlH_4还原,得到1,8-辛二醇,再用Ag_2CO_3硅藻土选择性氧化得8-羟基,最后用乙酸酐乙酰化,与丙二酸缩合,水解得到目的化合物10-羟基-2-癸烯酸。收藏指正
2.Result: Four compounds were isolated from the petroleum ether soluble portion,identified as 28-aldehyde-taraxerenone(1),28-hydroxy-taraxerenone(2),epi-friedelanol(3), 4-methyl stigmast-7-en-3-ol(4).
结果:从石油醚部位分离鉴定了4个化合物:3-羰基-14-taraxeren-28-(1),3-羰基-14-taraxeren-28-醇(2),表无羁萜醇(3),4-甲基-豆甾-7-烯-3-醇(4);收藏指正
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