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1.The microtopography and composition of V_2O_5TiO_2/α-Al_2O_3 catalysts before and after selective oxidation of hydrocarbons were investigated using scanning electron microscope(SEM)and energy dispersive spectrometer (EDS). It is observed that after prolonged heating of the catalysts at the hotpoint region in the reactor, the sodium ions in the adhesive used for the preparation of the carrier migrated to the catalyst surface and reacted with the active componet forming needles ofsodium vanadate, and thus affecting the catalyst performance.
用扫描电镜和能谱仪对V_2O_5-TiO_2/a-Al_2O_3催化剂反应前后的显微形貌和组成进行观察和分析,观察到催化剂由于在反应器热点区长期受热,制备载体所用粘结剂成份中的钠离子向催化剂表面迁移,与活性组份作用,形成钒酸钠针状物,从而影响了催化剂的反应性能。收藏指正
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