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1.Firstly, with the help of angular momentum coupling theory, the Hamiltonian for multi-electron adorns is rewritten in terms of spherical tensors. The advantage of this form is that the radial, angular and spin parts are separated completely, which makes it easy to calculate the angular matrix elements by means of irreducible tensor.
首先,借助角动量耦合理论,将多电子原子哈密顿算符中的自旋-自旋、自旋-其它轨道以及轨道-轨道相互作用全部改用球张量表示,这种球张量形式的优点在于已将原子哈密顿算符中的径向、角向和自旋部分完全分开,从而便于计算矩阵元,而且角向矩阵元可以方便地利用不可约张量理论来进行计算。收藏指正
2.In chapter two, with the help of angular momentum coupling theory, the Hamiltonian for multi-electron atoms is rewritten in form of spherical tensors operators. The advantage of this form is that the radial, angular and spin parts are separated completely, which makes it easy to calculate the angular matrix elements by means of irreducible tensor.
在第二章中,借助角动量耦合理论,将多电子原子哈密顿算符中的自旋-自旋、自旋-其它轨道以及轨道-轨道相互作用全部改用球张量表示,这种球张量形式的优点在于将原子哈密顿算符中的径向、角向和自旋部分完全分开,从而便于计算矩阵元,而且角向矩阵元可以方便地利用不可约张量理论来计算。收藏指正
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