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1.When the reaction conditions were reacting temperature of 30-55 ℃, In3+ concentration<150 g/L, sodium hydroxide concentration < 250 g/L,and pH value of 10-11.5, experimental results show that CIO powder has cubic structure, well distribution, finer dispersing in matrix, CuO:In2O3 (weight) =70:30, the mean grain size is about 27.815 nm and specific area 42.06 m2/g.
反应温度为30-55℃,In3+浓度<150 g/L,NaOH浓度< 250g/L,终点pH为10-11.5的条件下,实验结果表明:得到的纳米CIO粉末颗粒呈球状,团聚少、分散性好,CuO:In2O3(重量)=70:30,其粉体的晶粒尺寸为27.815 nm,比表面积42.06 m2/g。收藏指正
2.A novel dimethacrylates monomer,9,9′-bis(4-hydroxy-phenyl) fluorenyl diglycidyl methacrylate(HPFDM) with molecular weight is 634, was prepared by epoxying 9,9′-bis(4-hydroxy-phenyl) fluoenyl(9′9-HPF) with epoxy chloropropane,and then further reacting with methacrylic acid. The resinbased root canal sealer(NRCS) was made of this novel monomer as one of chief component.
以9,9′-二-(4-羟基-苯基)芴(9′9-HPF)为原料,用环氧氯丙烷将其环氧化后,再与甲基丙烯酸反应,合成了相对分子质量为634的双甲基丙烯酸酯类新单体HPFDM,并以该单体为共聚单体制备了新型树脂基质根管封闭剂NRCS。收藏指正
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