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1.It is obvious from experimental results that ln ρ is linear against T -1/2 . With increasing acidity of protonic acids ,doping concentration and the synthesizing concentration of dopant, the resistivity of the samples decreases, and the magnetic susceptibility can be written as a sum of a temperature independent Pauli spin susceptibility term and a Curie law term.
实验结果表明 ,lnρ和T- 1 2 呈线性关系 ,不同对阴离子对聚苯胺的电阻率影响很大 ,随着质子酸掺杂浓度以及苯胺单体与质子酸聚合时反应浓度的增大 ,聚苯胺的电阻率明显减小 ; 而且 ,其磁化率可以表示为与温度无关的泡利顺磁性和符合居里定律的顺磁性之和 .收藏指正
2.Variable-temperature (4. 2~300k) magnetic susceptibility measurements ars recorded for[(VO)_2(TPHA)(H_2O)_2(Me_2bpy)_2] (Ac)_2. The exchange integral, J,is found to be-42. 7cm~(-1). This indicates ah antiferromagnetic spin-exchange interaction between the VO(Ⅱ) ions.
测定了配合物[(VO)_2(TPHA)(H_2O)_2(Me_2bpy)_2](Ac)_2的变温磁化率(4.2~300K),求得交换积分J=-42.7cm~(-1),结果表明,双核VO(Ⅱ)配合物具有反铁磁自旋磁交换作用。收藏指正
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