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1.As indicated by structural analysis, the backbone of 13 is a one-dimensional linear chain which is comprised of alternating [Nb_2O_3F_8]~4- anions and Cd(C_3H_4N_2)_2~2+ Bond valence sum displays that 01, 03 and F3 have much more negative charge, so they act as bridge ligands.
单晶结构分析表明,配合物13的骨架为一维线性链,由[Nb_2O_3F_8]~(4-)和Cd(C_3H_4N_2)_2~(2+)交替连接而成。 键价计算表明,01、03和F3上的剩余负电荷更多,因而它们充当联配体。收藏指正
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